Tin-free enantioselective radical reactions using silanes

Mukund P. Sibi; Yong Hua Yang; Sunggi Lee

doi:10.1021/ol802154d

Tin-free enantioselective radical reactions using silanes

Mukund P. Sibi, Yong Hua Yang, Sunggi Lee

Department of Physics and Chemistry

North Dakota State University

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

(Chemical Equation Presented) Readily available hexyl silane is an excellent choice as a H-atom donor and a chain carrier in Lewis acid mediated enantioselective radical reactions. Conjugate radical additions to α,β-unsaturated imides at room temperature proceed in good yields and excellent enantioselectivities.

Original language	English
Pages (from-to)	5349-5352
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	23
DOIs	https://doi.org/10.1021/ol802154d
State	Published - 2008

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title = "Tin-free enantioselective radical reactions using silanes",

abstract = "(Chemical Equation Presented) Readily available hexyl silane is an excellent choice as a H-atom donor and a chain carrier in Lewis acid mediated enantioselective radical reactions. Conjugate radical additions to α,β-unsaturated imides at room temperature proceed in good yields and excellent enantioselectivities.",

author = "Sibi, {Mukund P.} and Yang, {Yong Hua} and Sunggi Lee",

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doi = "10.1021/ol802154d",

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journal = "Organic Letters",

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T1 - Tin-free enantioselective radical reactions using silanes

AU - Sibi, Mukund P.

AU - Yang, Yong Hua

AU - Lee, Sunggi

PY - 2008

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N2 - (Chemical Equation Presented) Readily available hexyl silane is an excellent choice as a H-atom donor and a chain carrier in Lewis acid mediated enantioselective radical reactions. Conjugate radical additions to α,β-unsaturated imides at room temperature proceed in good yields and excellent enantioselectivities.

AB - (Chemical Equation Presented) Readily available hexyl silane is an excellent choice as a H-atom donor and a chain carrier in Lewis acid mediated enantioselective radical reactions. Conjugate radical additions to α,β-unsaturated imides at room temperature proceed in good yields and excellent enantioselectivities.

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U2 - 10.1021/ol802154d

DO - 10.1021/ol802154d

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VL - 10

SP - 5349

EP - 5352

JO - Organic Letters

JF - Organic Letters

IS - 23

ER -

Tin-free enantioselective radical reactions using silanes

Abstract

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