The Giese reaction of alkyl bromides using amine carboxyboranes

Changhee Park; Seyun Gi; Seongkyeong Yoon; Seong Jung Kwon; Sunggi Lee

doi:10.1039/d4qo02325k

The Giese reaction of alkyl bromides using amine carboxyboranes

Changhee Park
, Seyun Gi
, Seongkyeong Yoon
, Seong Jung Kwon
, Sunggi Lee

Department of Physics and Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.

Original language	English
Pages (from-to)	1874-1878
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	12
Issue number	6
DOIs	https://doi.org/10.1039/d4qo02325k
State	Published - 9 Jan 2025

Bibliographical note

Publisher Copyright:
© 2025 The Royal Society of Chemistry.

Access to Document

10.1039/d4qo02325k

Cite this

@article{0dc970ec26fc474ead2d58217eb48f1f,

title = "The Giese reaction of alkyl bromides using amine carboxyboranes",

abstract = "Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.",

author = "Changhee Park and Seyun Gi and Seongkyeong Yoon and Kwon, \{Seong Jung\} and Sunggi Lee",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

month = jan,

day = "9",

doi = "10.1039/d4qo02325k",

language = "English",

volume = "12",

pages = "1874--1878",

journal = "Organic Chemistry Frontiers",

issn = "2052-4110",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - The Giese reaction of alkyl bromides using amine carboxyboranes

AU - Park, Changhee

AU - Gi, Seyun

AU - Yoon, Seongkyeong

AU - Kwon, Seong Jung

AU - Lee, Sunggi

PY - 2025/1/9

Y1 - 2025/1/9

N2 - Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.

AB - Amine carboxyborane enabled efficient halogen atom transfer (XAT) with 1°, 2°, and 3° alkyl bromides, resulting in Giese addition products with various electron-deficient double bonds. Moreover, direct addition of several boryl radicals was also possible using several ligated carboxyboranes.

UR - https://www.scopus.com/pages/publications/86000746295

U2 - 10.1039/d4qo02325k

DO - 10.1039/d4qo02325k

M3 - Article

AN - SCOPUS:86000746295

SN - 2052-4110

VL - 12

SP - 1874

EP - 1878

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 6

ER -

The Giese reaction of alkyl bromides using amine carboxyboranes

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this