Rapid Cs⁺ Capture via Multiple Supramolecular Interactions in Anionic Metal–Organic Framework Isomers

Metal–organic frameworks (MOFs) provide an ideal platform for ion exchange due to their high porosity and structural designability; however, developing MOFs that have the essential characteristics for ion exchange remains a challenge. These crucial features include fast kinetics, selectivity, and stability. We present two anionic isomers, DGIST-2 (2D) and DGIST-3 (3D), comprising distinctly arranged 5-(1,8-naphthalimido)isophthalate ligands and In³⁺ cations. Interestingly, in protic solvents, DGIST-2 transforms into a hydrolytically stable crystalline phase, DGIST-2′. DGIST-2′ and DGIST-3 exhibit rapid Cs⁺ adsorption kinetics, as well as high Cs⁺ affinity in the presence of competing cations. The mechanism for rapid and selective sorption is explored based on the results of single-crystal X-ray diffraction analysis of Cs⁺-incorporated DGIST-3. In Cs⁺-containing solutions, the loosely incorporated dimethylammonium countercation of the anionic framework is replaced by Cs⁺, which is held in the hydrophobic cavity by supramolecular ion–ion and cation−π interactions.