Prototype system of rocking-chair zn-ion battery adopting zinc chevrel phase anode and rhombohedral zinc hexacyanoferrate cathode

Munseok S. Chae; Seung Tae Hong

doi:10.3390/batteries5010003

Prototype system of rocking-chair zn-ion battery adopting zinc chevrel phase anode and rhombohedral zinc hexacyanoferrate cathode

Munseok S. Chae
, Seung Tae Hong

Department of Energy and Science and Engineering

Daegu Gyeongbuk Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Zinc-ion batteries (ZIBs) have received attention as one type of multivalent-ion batteries due to their potential applications in large-scale energy storage systems. Here we report a prototype of rocking-chair ZIB system employing Zn₂Mo₆S₈ (zinc Chevrel phase) as an anode operating at 0.35 V, and K_0.02(H₂O)_0.22Zn_2.94[Fe(CN)₆]₂ (rhombohedral zinc Prussian-blue analogue) as a cathode operating at 1.75 V (vs. Zn/Zn²⁺) in ZnSO₄ aqueous electrolyte. This type of cell has a benefit due to its intrinsic zinc-dendrite-free nature. The cell is designed to be positive-limited with a capacity of 62.3 mAh g⁻¹. The full-cell shows a reversible cycle with an average discharge cell voltage of ~1.40 V, demonstrating a successful rocking-chair zinc-ion battery system.

Original language	English
Article number	3
Journal	Batteries
Volume	5
Issue number	1
DOIs	https://doi.org/10.3390/batteries5010003
State	Published - Mar 2019

Bibliographical note

Publisher Copyright:
© 2019 by the authors. Licensee MDPI, Basel, Switzerland.

Keywords

Chevrel phase
Multivalent-ion battery
Prussian blue analogue
Rocking-chair battery
Zinc hexacyanoferrate
Zinc-ion battery

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@article{19845062856f4e3eb204bbbf6090e753,

title = "Prototype system of rocking-chair zn-ion battery adopting zinc chevrel phase anode and rhombohedral zinc hexacyanoferrate cathode",

abstract = "Zinc-ion batteries (ZIBs) have received attention as one type of multivalent-ion batteries due to their potential applications in large-scale energy storage systems. Here we report a prototype of rocking-chair ZIB system employing Zn2Mo6S8 (zinc Chevrel phase) as an anode operating at 0.35 V, and K0.02(H2O)0.22Zn2.94[Fe(CN)6]2 (rhombohedral zinc Prussian-blue analogue) as a cathode operating at 1.75 V (vs. Zn/Zn2+) in ZnSO4 aqueous electrolyte. This type of cell has a benefit due to its intrinsic zinc-dendrite-free nature. The cell is designed to be positive-limited with a capacity of 62.3 mAh g−1. The full-cell shows a reversible cycle with an average discharge cell voltage of \textasciitilde{}1.40 V, demonstrating a successful rocking-chair zinc-ion battery system.",

keywords = "Chevrel phase, Multivalent-ion battery, Prussian blue analogue, Rocking-chair battery, Zinc hexacyanoferrate, Zinc-ion battery",

author = "Chae, \{Munseok S.\} and Hong, \{Seung Tae\}",

note = "Publisher Copyright: {\textcopyright} 2019 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2019",

month = mar,

doi = "10.3390/batteries5010003",

language = "English",

volume = "5",

journal = "Batteries",

issn = "2313-0105",

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T1 - Prototype system of rocking-chair zn-ion battery adopting zinc chevrel phase anode and rhombohedral zinc hexacyanoferrate cathode

AU - Chae, Munseok S.

AU - Hong, Seung Tae

PY - 2019/3

Y1 - 2019/3

N2 - Zinc-ion batteries (ZIBs) have received attention as one type of multivalent-ion batteries due to their potential applications in large-scale energy storage systems. Here we report a prototype of rocking-chair ZIB system employing Zn2Mo6S8 (zinc Chevrel phase) as an anode operating at 0.35 V, and K0.02(H2O)0.22Zn2.94[Fe(CN)6]2 (rhombohedral zinc Prussian-blue analogue) as a cathode operating at 1.75 V (vs. Zn/Zn2+) in ZnSO4 aqueous electrolyte. This type of cell has a benefit due to its intrinsic zinc-dendrite-free nature. The cell is designed to be positive-limited with a capacity of 62.3 mAh g−1. The full-cell shows a reversible cycle with an average discharge cell voltage of ~1.40 V, demonstrating a successful rocking-chair zinc-ion battery system.

AB - Zinc-ion batteries (ZIBs) have received attention as one type of multivalent-ion batteries due to their potential applications in large-scale energy storage systems. Here we report a prototype of rocking-chair ZIB system employing Zn2Mo6S8 (zinc Chevrel phase) as an anode operating at 0.35 V, and K0.02(H2O)0.22Zn2.94[Fe(CN)6]2 (rhombohedral zinc Prussian-blue analogue) as a cathode operating at 1.75 V (vs. Zn/Zn2+) in ZnSO4 aqueous electrolyte. This type of cell has a benefit due to its intrinsic zinc-dendrite-free nature. The cell is designed to be positive-limited with a capacity of 62.3 mAh g−1. The full-cell shows a reversible cycle with an average discharge cell voltage of ~1.40 V, demonstrating a successful rocking-chair zinc-ion battery system.

KW - Chevrel phase

KW - Multivalent-ion battery

KW - Prussian blue analogue

KW - Rocking-chair battery

KW - Zinc hexacyanoferrate

KW - Zinc-ion battery

UR - https://www.scopus.com/pages/publications/85065580376

U2 - 10.3390/batteries5010003

DO - 10.3390/batteries5010003

M3 - Article

AN - SCOPUS:85065580376

SN - 2313-0105

VL - 5

JO - Batteries

JF - Batteries

IS - 1

M1 - 3

ER -

Prototype system of rocking-chair zn-ion battery adopting zinc chevrel phase anode and rhombohedral zinc hexacyanoferrate cathode

Abstract

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Keywords

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