Oxocyclohexadienylidene-substituted subporphyrins

Shin Ya Hayashi; Jooyoung Sung; Young Mo Sung; Yasuhide Inokuma; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.201006449

Oxocyclohexadienylidene-substituted subporphyrins

Shin Ya Hayashi, Jooyoung Sung, Young Mo Sung, Yasuhide Inokuma, Dongho Kim, Atsuhiro Osuka

Department of Physics and Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso-tris(3,5-di-tert-butyl-4-hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3. These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3.

Original language	English
Pages (from-to)	3253-3256
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	14
DOIs	https://doi.org/10.1002/anie.201006449
State	Published - 28 Mar 2011

Keywords

conjugated systems
delocalization
oxoporphyrinogen
porphyrinoids
subporphyrins

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10.1002/anie.201006449

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abstract = "Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso-tris(3,5-di-tert-butyl-4-hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3. These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3.",

keywords = "conjugated systems, delocalization, oxoporphyrinogen, porphyrinoids, subporphyrins",

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T1 - Oxocyclohexadienylidene-substituted subporphyrins

AU - Hayashi, Shin Ya

AU - Sung, Jooyoung

AU - Sung, Young Mo

AU - Inokuma, Yasuhide

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2011/3/28

Y1 - 2011/3/28

N2 - Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso-tris(3,5-di-tert-butyl-4-hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3. These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3.

AB - Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso-tris(3,5-di-tert-butyl-4-hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3. These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3.

KW - conjugated systems

KW - delocalization

KW - oxoporphyrinogen

KW - porphyrinoids

KW - subporphyrins

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M3 - Article

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ER -

Oxocyclohexadienylidene-substituted subporphyrins

Abstract

Keywords

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