Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries

Xia Cao; Lianfeng Zou; Bethany E. Matthews; Linchao Zhang; Xinzi He; Xiaodi Ren; Mark H. Engelhard; Sarah D. Burton; Patrick Z. El-Khoury; Hyung Seok Lim; Chaojiang Niu; Hongkyung Lee; Chunsheng Wang; Bruce W. Arey; Chongmin Wang; Jie Xiao; Jun Liu; Wu Xu; Ji Guang Zhang

doi:10.1016/j.ensm.2020.08.035

Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries

Xia Cao, Lianfeng Zou, Bethany E. Matthews, Linchao Zhang, Xinzi He, Xiaodi Ren, Mark H. Engelhard, Sarah D. Burton, Patrick Z. El-Khoury, Hyung Seok Lim, Chaojiang Niu, Hongkyung Lee, Chunsheng Wang, Bruce W. Arey, Chongmin Wang, Jie Xiao, Jun Liu, Wu Xu, Ji Guang Zhang

Department of Energy and Science and Engineering

Research output: Contribution to journal › Article › peer-review

108 Scopus citations

Original language	English
Pages (from-to)	76-84
Number of pages	9
Journal	Energy Storage Materials
Volume	34
DOIs	https://doi.org/10.1016/j.ensm.2020.08.035
State	Published - Jan 2021

Bibliographical note

Funding Information:
This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Office, of the U.S. Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. DE- AC05–76RL01830. The SEM, TEM, Raman and XPS measurements were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the DOE under Contract DE-AC05–76RL01830. The LiFSI salt was provided by Dr. Kazuhiko Murata of Nippon Shokubai Co., Ltd.

Funding Information:
This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Office, of the U.S. Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. DE- AC05?76RL01830. The SEM, TEM, Raman and XPS measurements were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the DOE under Contract DE-AC05?76RL01830. The LiFSI salt was provided by Dr. Kazuhiko Murata of Nippon Shokubai Co. Ltd.

Keywords

Electrolyte
High voltage
Lithium anode
Lithium metal battery
Localized high-concentration electrolyte
Tris(2,2,2-trifluoroethyl) orthoformate

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ensm.2020.08.035

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Cao, X., Zou, L., Matthews, B. E., Zhang, L., He, X., Ren, X., Engelhard, M. H., Burton, S. D., El-Khoury, P. Z., Lim, H. S., Niu, C., Lee, H., Wang, C., Arey, B. W., Wang, C., Xiao, J., Liu, J., Xu, W., & Zhang, J. G. (2021). Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries. Energy Storage Materials, 34, 76-84. https://doi.org/10.1016/j.ensm.2020.08.035

@article{3177edf5dae5490eb385523ce7071f76,

title = "Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries",

keywords = "Electrolyte, High voltage, Lithium anode, Lithium metal battery, Localized high-concentration electrolyte, Tris(2,2,2-trifluoroethyl) orthoformate",

author = "Xia Cao and Lianfeng Zou and Matthews, \{Bethany E.\} and Linchao Zhang and Xinzi He and Xiaodi Ren and Engelhard, \{Mark H.\} and Burton, \{Sarah D.\} and El-Khoury, \{Patrick Z.\} and Lim, \{Hyung Seok\} and Chaojiang Niu and Hongkyung Lee and Chunsheng Wang and Arey, \{Bruce W.\} and Chongmin Wang and Jie Xiao and Jun Liu and Wu Xu and Zhang, \{Ji Guang\}",

note = "Funding Information: This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Office, of the U.S. Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. DE- AC05–76RL01830. The SEM, TEM, Raman and XPS measurements were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the DOE under Contract DE-AC05–76RL01830. The LiFSI salt was provided by Dr. Kazuhiko Murata of Nippon Shokubai Co., Ltd. Funding Information: This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Office, of the U.S. Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. DE- AC05?76RL01830. The SEM, TEM, Raman and XPS measurements were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the DOE under Contract DE-AC05?76RL01830. The LiFSI salt was provided by Dr. Kazuhiko Murata of Nippon Shokubai Co. Ltd.",

year = "2021",

month = jan,

doi = "10.1016/j.ensm.2020.08.035",

language = "English",

volume = "34",

pages = "76--84",

journal = "Energy Storage Materials",

issn = "2405-8297",

publisher = "Elsevier B.V.",

}

Cao, X, Zou, L, Matthews, BE, Zhang, L, He, X, Ren, X, Engelhard, MH, Burton, SD, El-Khoury, PZ, Lim, HS, Niu, C, Lee, H, Wang, C, Arey, BW, Wang, C, Xiao, J, Liu, J, Xu, W & Zhang, JG 2021, 'Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries', Energy Storage Materials, vol. 34, pp. 76-84. https://doi.org/10.1016/j.ensm.2020.08.035

TY - JOUR

T1 - Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries

AU - Cao, Xia

AU - Zou, Lianfeng

AU - Matthews, Bethany E.

AU - Zhang, Linchao

AU - He, Xinzi

AU - Ren, Xiaodi

AU - Engelhard, Mark H.

AU - Burton, Sarah D.

AU - El-Khoury, Patrick Z.

AU - Lim, Hyung Seok

AU - Niu, Chaojiang

AU - Lee, Hongkyung

AU - Wang, Chunsheng

AU - Arey, Bruce W.

AU - Wang, Chongmin

AU - Xiao, Jie

AU - Liu, Jun

AU - Xu, Wu

AU - Zhang, Ji Guang

N1 - Funding Information: This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Office, of the U.S. Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. DE- AC05–76RL01830. The SEM, TEM, Raman and XPS measurements were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the DOE under Contract DE-AC05–76RL01830. The LiFSI salt was provided by Dr. Kazuhiko Murata of Nippon Shokubai Co., Ltd. Funding Information: This work is supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Office, of the U.S. Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. DE- AC05?76RL01830. The SEM, TEM, Raman and XPS measurements were performed using EMSL (grid.436923.9), a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the DOE under Contract DE-AC05?76RL01830. The LiFSI salt was provided by Dr. Kazuhiko Murata of Nippon Shokubai Co. Ltd.

PY - 2021/1

Y1 - 2021/1

KW - Electrolyte

KW - High voltage

KW - Lithium anode

KW - Lithium metal battery

KW - Localized high-concentration electrolyte

KW - Tris(2,2,2-trifluoroethyl) orthoformate

UR - https://www.scopus.com/pages/publications/85091380659

U2 - 10.1016/j.ensm.2020.08.035

DO - 10.1016/j.ensm.2020.08.035

M3 - Article

AN - SCOPUS:85091380659

SN - 2405-8297

VL - 34

SP - 76

EP - 84

JO - Energy Storage Materials

JF - Energy Storage Materials

ER -

Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries

Bibliographical note

Keywords

UN SDGs

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