Abstract
We report a one-pot sulfa-Michael addition reaction using a disulfide and a pyridine-borane complex under blue light irradiation. This novel synthetic approach has a broad substrate scope and a high functional group tolerance. Mechanistic studies suggest that sequential radical and ionic processes provide a practical solution for constructing carbon–sulfur bonds.
| Original language | English |
|---|---|
| Pages (from-to) | 951-954 |
| Number of pages | 4 |
| Journal | Bulletin of the Korean Chemical Society |
| Volume | 43 |
| Issue number | 7 |
| DOIs | |
| State | Published - Jul 2022 |
Bibliographical note
Publisher Copyright:© 2022 Korean Chemical Society, Seoul & Wiley-VCH GmbH.
Keywords
- disulfide homolysis
- pyridine-borane complex
- sulfa-Michael addition reaction
- thiyl radical
- visible light irradiation