Nanocomposite single ion conductor based on organic-inorganic hybrid

Nam Soon Choi; Yong Min Lee; Baik Hyeon Lee; Je An Lee; Jung Ki Park

doi:10.1016/j.ssi.2003.06.002

Nanocomposite single ion conductor based on organic-inorganic hybrid

Nam Soon Choi
, Yong Min Lee
, Baik Hyeon Lee
, Je An Lee
, Jung Ki Park

Department of Energy and Science and Engineering

Korea Advanced Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

New nanosized silica with the propane lithium sulfonate was systematically synthesized as the lithium ions source of the single ion conductor. The cross-linked single ion conductor based on the PEGDMA, the modified silica, and the plasticizer (PC/DMSO, 50/50 w/w) was prepared by UV-curing. Ionic conductivity and interfacial stability toward the lithium electrode of the cross-linked nanocomposite single ion conductor were investigated by varying the modified silica content. The ionic conductivity of the cross-linked single ion conductor showed maximum trend with the modified silica content. The ionic conductivity of the cross-linked single ion conductor with 30% modified silica was 2.2 × 10^-4 S/cm at 25°C. Interfacial stability between the cross-linked nanocomposite single ion conductor and the lithium electrode was enhanced by introducing the modified silica.

Original language	English
Pages (from-to)	293-299
Number of pages	7
Journal	Solid State Ionics
Volume	167
Issue number	3-4
DOIs	https://doi.org/10.1016/j.ssi.2003.06.002
State	Published - 27 Feb 2004

Keywords

Interfacial stability
Ion conductivity
Nanocomposite single ion conductor
Nanosized fumed silica
Sulfonation

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10.1016/j.ssi.2003.06.002

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title = "Nanocomposite single ion conductor based on organic-inorganic hybrid",

abstract = "New nanosized silica with the propane lithium sulfonate was systematically synthesized as the lithium ions source of the single ion conductor. The cross-linked single ion conductor based on the PEGDMA, the modified silica, and the plasticizer (PC/DMSO, 50/50 w/w) was prepared by UV-curing. Ionic conductivity and interfacial stability toward the lithium electrode of the cross-linked nanocomposite single ion conductor were investigated by varying the modified silica content. The ionic conductivity of the cross-linked single ion conductor showed maximum trend with the modified silica content. The ionic conductivity of the cross-linked single ion conductor with 30\% modified silica was 2.2 × 10-4 S/cm at 25°C. Interfacial stability between the cross-linked nanocomposite single ion conductor and the lithium electrode was enhanced by introducing the modified silica.",

keywords = "Interfacial stability, Ion conductivity, Nanocomposite single ion conductor, Nanosized fumed silica, Sulfonation",

author = "Choi, \{Nam Soon\} and Lee, \{Yong Min\} and Lee, \{Baik Hyeon\} and Lee, \{Je An\} and Park, \{Jung Ki\}",

year = "2004",

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doi = "10.1016/j.ssi.2003.06.002",

language = "English",

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pages = "293--299",

journal = "Solid State Ionics",

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}

TY - JOUR

T1 - Nanocomposite single ion conductor based on organic-inorganic hybrid

AU - Choi, Nam Soon

AU - Lee, Yong Min

AU - Lee, Baik Hyeon

AU - Lee, Je An

AU - Park, Jung Ki

PY - 2004/2/27

Y1 - 2004/2/27

N2 - New nanosized silica with the propane lithium sulfonate was systematically synthesized as the lithium ions source of the single ion conductor. The cross-linked single ion conductor based on the PEGDMA, the modified silica, and the plasticizer (PC/DMSO, 50/50 w/w) was prepared by UV-curing. Ionic conductivity and interfacial stability toward the lithium electrode of the cross-linked nanocomposite single ion conductor were investigated by varying the modified silica content. The ionic conductivity of the cross-linked single ion conductor showed maximum trend with the modified silica content. The ionic conductivity of the cross-linked single ion conductor with 30% modified silica was 2.2 × 10-4 S/cm at 25°C. Interfacial stability between the cross-linked nanocomposite single ion conductor and the lithium electrode was enhanced by introducing the modified silica.

AB - New nanosized silica with the propane lithium sulfonate was systematically synthesized as the lithium ions source of the single ion conductor. The cross-linked single ion conductor based on the PEGDMA, the modified silica, and the plasticizer (PC/DMSO, 50/50 w/w) was prepared by UV-curing. Ionic conductivity and interfacial stability toward the lithium electrode of the cross-linked nanocomposite single ion conductor were investigated by varying the modified silica content. The ionic conductivity of the cross-linked single ion conductor showed maximum trend with the modified silica content. The ionic conductivity of the cross-linked single ion conductor with 30% modified silica was 2.2 × 10-4 S/cm at 25°C. Interfacial stability between the cross-linked nanocomposite single ion conductor and the lithium electrode was enhanced by introducing the modified silica.

KW - Interfacial stability

KW - Ion conductivity

KW - Nanocomposite single ion conductor

KW - Nanosized fumed silica

KW - Sulfonation

UR - https://www.scopus.com/pages/publications/1842841989

U2 - 10.1016/j.ssi.2003.06.002

DO - 10.1016/j.ssi.2003.06.002

M3 - Article

AN - SCOPUS:1842841989

SN - 0167-2738

VL - 167

SP - 293

EP - 299

JO - Solid State Ionics

JF - Solid State Ionics

IS - 3-4

ER -

Nanocomposite single ion conductor based on organic-inorganic hybrid

Abstract

Keywords

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