N -Triflylphosphorimidoyl Trichloride: A Versatile Reagent for the Synthesis of Strong Chiral Bronsted Acids

Sunggi Lee; Philip S.J. Kaib; Benjamin List

doi:10.1055/s-0036-1588782

N -Triflylphosphorimidoyl Trichloride: A Versatile Reagent for the Synthesis of Strong Chiral Bronsted Acids

Sunggi Lee, Philip S.J. Kaib, Benjamin List

Department of Physics and Chemistry

Max Planck Institute for Coal Research

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A series of strong Bronsted acids has been synthesized in high yields using N -triflylphosphorimidoyl trichloride as reagent. The syntheses proceed efficiently with electron-rich, electron-deficient, and sterically hindered substrates.

Original language	English
Pages (from-to)	1478-1480
Number of pages	3
Journal	Synlett
Volume	28
Issue number	12
DOIs	https://doi.org/10.1055/s-0036-1588782
State	Published - 24 Jul 2017

Bibliographical note

Publisher Copyright:
© 2017 Georg Thieme Verlag Stuttgart.New York-Synlett.

Keywords

Bronsted acid
N -triflylphosphoramide
N -triflylphosphorimidoyl trichloride
N -triflylthiophosphoramide
N, N ′-bis(triflyl)phosphoramidimidate

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title = "N -Triflylphosphorimidoyl Trichloride: A Versatile Reagent for the Synthesis of Strong Chiral Bronsted Acids",

abstract = "A series of strong Bronsted acids has been synthesized in high yields using N -triflylphosphorimidoyl trichloride as reagent. The syntheses proceed efficiently with electron-rich, electron-deficient, and sterically hindered substrates.",

keywords = "Bronsted acid, N -triflylphosphoramide, N -triflylphosphorimidoyl trichloride, N -triflylthiophosphoramide, N, N ′-bis(triflyl)phosphoramidimidate",

author = "Sunggi Lee and Kaib, {Philip S.J.} and Benjamin List",

note = "Publisher Copyright: {\textcopyright} 2017 Georg Thieme Verlag Stuttgart.New York-Synlett.",

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T2 - A Versatile Reagent for the Synthesis of Strong Chiral Bronsted Acids

AU - Lee, Sunggi

AU - Kaib, Philip S.J.

AU - List, Benjamin

PY - 2017/7/24

Y1 - 2017/7/24

N2 - A series of strong Bronsted acids has been synthesized in high yields using N -triflylphosphorimidoyl trichloride as reagent. The syntheses proceed efficiently with electron-rich, electron-deficient, and sterically hindered substrates.

AB - A series of strong Bronsted acids has been synthesized in high yields using N -triflylphosphorimidoyl trichloride as reagent. The syntheses proceed efficiently with electron-rich, electron-deficient, and sterically hindered substrates.

KW - Bronsted acid

KW - N -triflylphosphoramide

KW - N -triflylphosphorimidoyl trichloride

KW - N -triflylthiophosphoramide

KW - N, N ′-bis(triflyl)phosphoramidimidate

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U2 - 10.1055/s-0036-1588782

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M3 - Article

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VL - 28

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JO - Synlett

JF - Synlett

IS - 12

ER -

N -Triflylphosphorimidoyl Trichloride: A Versatile Reagent for the Synthesis of Strong Chiral Bronsted Acids

Abstract

Bibliographical note

Keywords

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