Mixed morphology of TiO 2 nanotube and TiO 2 nanoparticles for dye sensitized solar cells

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Abstract

One limitation factor in improving device performances of dye-sensitized solar cells is the random electron diffusion inside of the working electrode composed of TiO 2 nanocrystalline particles. Recently, application of highly ordered TiO 2 nanotubes (TNT) to DSCs has attracted considerable interest due to the shorter electron diffusion passway in TiO 2 layers. However, the performance of TNT-based DSCs is lower than that of TNP-based solar cell because of the back side illumination and the thick barrier layer and so on. One of the strategies to increase the power conversion efficiency is increasing the surface area of the TNT without growth its length, because electron has a limitation length of diffusion. Recently, the effect of the TiCl 4 treatment on TNT is reported to attach small TiO 2 particle on TNT surface. In this work, we investigated this method to induce TiO 2 particles on the surface of bare TNTs using TiCl 4 treatment.

Original languageEnglish
JournalACS National Meeting Book of Abstracts
StatePublished - 2011
Event242nd ACS National Meeting and Exposition - Denver, CO, United States
Duration: 28 Aug 20111 Sep 2011

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