Abstract
We describe meta-selective C-H functionalization of arylsilanes using a Si-tethered directing group. The current method enables a selective alkenylation of arenes bearing a variety of functional groups, and several electron-deficient olefins are also applicable as coupling partners. Further functional group transformations of the silicon-tethered directing group provide multisubstituted arenes efficiently.
Original language | English |
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Pages (from-to) | 5181-5185 |
Number of pages | 5 |
Journal | Organic Letters |
Volume | 24 |
Issue number | 28 |
DOIs | |
State | Published - 22 Jul 2022 |
Bibliographical note
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