Meta-Selective C-H Functionalization of Arylsilanes Using a Silicon Tethered Directing Group

Jaehan Bang, Seyun Gi, Yoonjung Lee, Kian L. Tan, Sunggi Lee

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

We describe meta-selective C-H functionalization of arylsilanes using a Si-tethered directing group. The current method enables a selective alkenylation of arenes bearing a variety of functional groups, and several electron-deficient olefins are also applicable as coupling partners. Further functional group transformations of the silicon-tethered directing group provide multisubstituted arenes efficiently.

Original languageEnglish
Pages (from-to)5181-5185
Number of pages5
JournalOrganic Letters
Volume24
Issue number28
DOIs
StatePublished - 22 Jul 2022

Bibliographical note

Publisher Copyright:
© 2022 American Chemical Society.

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