Length-dependent band-gap shift of TiO32- molecular wires embedded in zeolite ETS-10

Nak Cheon Jeong, Myoung Hee Lee, Kyung Byung Yoon

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

(Figure Presented) Mind the gap! The titanosilicate zeolite ETS-10 contains TiO32- molecular wires (see picture). A reliable method has been developed to synthesize high-quality ETS-10 crystals of various sizes. Measurements on the crystals allow the dependence of the band-gap energy on the length of the TiO32- wires to be elucidated.

Original languageEnglish
Pages (from-to)5868-5872
Number of pages5
JournalAngewandte Chemie - International Edition
Volume46
Issue number31
DOIs
StatePublished - 2007

Keywords

  • Electronic properties
  • Molecular wires
  • Zeolites

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