Immobilization of TiO2 on an ITO substrate to facilitate the photoelectrochemical degradation of an organic dye pollutant

Cham Kim, Jong Tae Kim, Ki Soo Kim, Seonju Jeong, Ho Young Kim, Yoon Soo Han

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39 Scopus citations

Abstract

In this study, we developed an immobilized TiO2 semiconductor on an ITO glass substrate (TiO2/ITO) and investigated its photocatalytic and electrochemical performance. The TiO2/ITO samples were prepared via a spin-coating process followed by calcination and were used for the photocatalytic or electrochemical degradation of an organic dye pollutant. The measured photocatalytic performance was comparable to that reported in previous publications; however, a remarkable result was obtained in our electrochemical system. The formation of hydroxyl radicals (OH{radical dot}) strongly dominated the electrochemical system, which resulted in outstanding degradation performance. Therefore, we propose a commercializable photoelectrochemical system that can maximize the degradation of pollutants in wastewater treatment plants.

Original languageEnglish
Pages (from-to)5715-5720
Number of pages6
JournalElectrochimica Acta
Volume54
Issue number24
DOIs
StatePublished - 1 Oct 2009

Bibliographical note

Funding Information:
Our work was financially supported by the DGIST Basic Research Program of the Ministry of Education, Science and Technology (MoEST) of Korea.

Keywords

  • Hydroxyl radical
  • Photoelectrochemical system
  • Spin-coating
  • TiO immobilization
  • TiO/ITO

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