Fabrication and optical properties of erbium-doped polymer films

Wook Hyun Kim; Soo Chool Lee; Kee Jeong Yang; Myung Seok Choi; Eui Sang Yoo; Yoon Soo Han

doi:10.1080/15421406.2010.497062

Fabrication and optical properties of erbium-doped polymer films

Wook Hyun Kim, Soo Chool Lee, Kee Jeong Yang, Myung Seok Choi, Eui Sang Yoo, Yoon Soo Han

Division of Energy Techonology

Research output: Contribution to journal › Article › peer-review

Abstract

The crosslinked, fluorinated, patterned and erbium (Er³⁺) doped polymer films were fabricated by UV-curing after a simple spin-coating. Er ³⁺-doped solutions containing Irgacure 819 used as a radical-type photoinitiator were prepared using erbium (III) trifluoromethane sulfonate as an erbium source, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate as a fluorinated monomer, trimethylolpropane triacrylate and Ebecyl 810 resin as a crosslinking agent with various weight ratios. The fluorinated polymer films fabricated in this study showed the excellent transmission property more than 80% over visible and NIR region, and high thermal decomposition temperature about 310°C sufficient for optical device applications. From these results, the Er ³⁺-doped polymer films developed in this study could be applied to optical telecommunication devices.

Original language	English
Pages (from-to)	156/[572]-164/[580]
Journal	Molecular Crystals and Liquid Crystals
Volume	532
DOIs	https://doi.org/10.1080/15421406.2010.497062
State	Published - 18 Oct 2010

Bibliographical note

Funding Information:
This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea.

Keywords

Amplifiers
UV curing
erbium
fluorinated monomer
fluorinated polymer
optical telecommunication device

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10.1080/15421406.2010.497062

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title = "Fabrication and optical properties of erbium-doped polymer films",

abstract = "The crosslinked, fluorinated, patterned and erbium (Er3+) doped polymer films were fabricated by UV-curing after a simple spin-coating. Er 3+-doped solutions containing Irgacure 819 used as a radical-type photoinitiator were prepared using erbium (III) trifluoromethane sulfonate as an erbium source, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate as a fluorinated monomer, trimethylolpropane triacrylate and Ebecyl 810 resin as a crosslinking agent with various weight ratios. The fluorinated polymer films fabricated in this study showed the excellent transmission property more than 80\% over visible and NIR region, and high thermal decomposition temperature about 310°C sufficient for optical device applications. From these results, the Er 3+-doped polymer films developed in this study could be applied to optical telecommunication devices.",

keywords = "Amplifiers, UV curing, erbium, fluorinated monomer, fluorinated polymer, optical telecommunication device",

author = "Kim, \{Wook Hyun\} and Lee, \{Soo Chool\} and Yang, \{Kee Jeong\} and Choi, \{Myung Seok\} and Yoo, \{Eui Sang\} and Han, \{Yoon Soo\}",

note = "Funding Information: This research was supported by a grant from the Fundamental R\&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea.",

year = "2010",

month = oct,

day = "18",

doi = "10.1080/15421406.2010.497062",

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T1 - Fabrication and optical properties of erbium-doped polymer films

AU - Kim, Wook Hyun

AU - Lee, Soo Chool

AU - Yang, Kee Jeong

AU - Choi, Myung Seok

AU - Yoo, Eui Sang

AU - Han, Yoon Soo

N1 - Funding Information: This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea.

PY - 2010/10/18

Y1 - 2010/10/18

N2 - The crosslinked, fluorinated, patterned and erbium (Er3+) doped polymer films were fabricated by UV-curing after a simple spin-coating. Er 3+-doped solutions containing Irgacure 819 used as a radical-type photoinitiator were prepared using erbium (III) trifluoromethane sulfonate as an erbium source, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate as a fluorinated monomer, trimethylolpropane triacrylate and Ebecyl 810 resin as a crosslinking agent with various weight ratios. The fluorinated polymer films fabricated in this study showed the excellent transmission property more than 80% over visible and NIR region, and high thermal decomposition temperature about 310°C sufficient for optical device applications. From these results, the Er 3+-doped polymer films developed in this study could be applied to optical telecommunication devices.

AB - The crosslinked, fluorinated, patterned and erbium (Er3+) doped polymer films were fabricated by UV-curing after a simple spin-coating. Er 3+-doped solutions containing Irgacure 819 used as a radical-type photoinitiator were prepared using erbium (III) trifluoromethane sulfonate as an erbium source, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate as a fluorinated monomer, trimethylolpropane triacrylate and Ebecyl 810 resin as a crosslinking agent with various weight ratios. The fluorinated polymer films fabricated in this study showed the excellent transmission property more than 80% over visible and NIR region, and high thermal decomposition temperature about 310°C sufficient for optical device applications. From these results, the Er 3+-doped polymer films developed in this study could be applied to optical telecommunication devices.

KW - Amplifiers

KW - UV curing

KW - erbium

KW - fluorinated monomer

KW - fluorinated polymer

KW - optical telecommunication device

UR - https://www.scopus.com/pages/publications/78649260655

U2 - 10.1080/15421406.2010.497062

DO - 10.1080/15421406.2010.497062

M3 - Article

AN - SCOPUS:78649260655

SN - 1542-1406

VL - 532

SP - 156/[572]-164/[580]

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

Fabrication and optical properties of erbium-doped polymer films

Abstract

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Keywords

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