Excellent thermal stability of Al2O3/ZrO 2/Al2O3 stack structure for metal-oxide-semiconductor gate dielectrics application

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Abstract

The thermal stability of a nanolaminate (Al2O 3/ZrO2/Al2O3) gate stack prepared by atomic layer chemical vapor deposition was investigated using medium-energy ion scattering spectroscopy, and x-ray photoelectron spectroscopy. We observed that the structure was stable up to 1000°C under ultrahigh vacuum conditions. However, annealing in a nitrogen or oxygen ambient at 1 atm yielded the formation of an interfacial Zr-Al silicate layer at much lower temperatures. The growth of the interfacial silicate layer could be significantly reduced during furnace annealing via the use of plasma nitridation.

Original languageEnglish
Pages (from-to)3385-3387
Number of pages3
JournalApplied Physics Letters
Volume80
Issue number18
DOIs
StatePublished - 6 May 2002

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