Electrochemical activities of Pt-Ru-Co and Pt-Ru-Ni electrocatalysts supported by a carbon fiber web

Jihye Kim; Beta Zenia Poliquit; Ho Seong Nam; Sang Hern Kim; Yong Min Lee; Kwang Man Kim; Jang Myoun Ko

doi:10.1016/j.cap.2011.06.014

Electrochemical activities of Pt-Ru-Co and Pt-Ru-Ni electrocatalysts supported by a carbon fiber web

Jihye Kim
, Beta Zenia Poliquit
, Ho Seong Nam
, Sang Hern Kim
, Yong Min Lee
, Kwang Man Kim
, Jang Myoun Ko

Department of Energy and Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Dynamic cyclic voltammetry is performed as functions of cycle number and potential window for the electrodeposition of Pt-Ru-Co and Pt-Ru-Ni catalysts on a carbon fiber (CF) web. Surface morphologies of the electrodeposited catalysts are observed by a scanning electron microscope. The electrochemical activity in methanol oxidation is examined by the cyclic voltammetry using a mixed aqueous solution of methanol as an electrolyte component. As the cycle number increases, both the current density and the amount of the electrodeposited metallic particles on the CF web are increased. The Pt-Ru-Ni/CF catalyst prepared in the potential range of -0.6 to 0.2 V and from the 1:2:2 mixed solution of H ₂PtCl₆, RuCl₃·3H₂O, and Ni(NO₃)₂·6H₂O, respectively, shows the higher current density, corresponding to the higher catalytic activity.

Original language	English
Pages (from-to)	254-258
Number of pages	5
Journal	Current Applied Physics
Volume	12
Issue number	1
DOIs	https://doi.org/10.1016/j.cap.2011.06.014
State	Published - Jan 2012

Bibliographical note

Funding Information:
This research was financially supported by the Ministry of Education, Science Technology (MEST) and National Research Foundation of Korea (NRF) through the Human Resource Training Project for Regional Innovation.

Keywords

Carbon fiber web
Cyclic voltammetry
Electrodeposition
Pt-Ru-Co
Pt-Ru-Ni

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10.1016/j.cap.2011.06.014

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title = "Electrochemical activities of Pt-Ru-Co and Pt-Ru-Ni electrocatalysts supported by a carbon fiber web",

abstract = "Dynamic cyclic voltammetry is performed as functions of cycle number and potential window for the electrodeposition of Pt-Ru-Co and Pt-Ru-Ni catalysts on a carbon fiber (CF) web. Surface morphologies of the electrodeposited catalysts are observed by a scanning electron microscope. The electrochemical activity in methanol oxidation is examined by the cyclic voltammetry using a mixed aqueous solution of methanol as an electrolyte component. As the cycle number increases, both the current density and the amount of the electrodeposited metallic particles on the CF web are increased. The Pt-Ru-Ni/CF catalyst prepared in the potential range of -0.6 to 0.2 V and from the 1:2:2 mixed solution of H 2PtCl6, RuCl3·3H2O, and Ni(NO3)2·6H2O, respectively, shows the higher current density, corresponding to the higher catalytic activity.",

keywords = "Carbon fiber web, Cyclic voltammetry, Electrodeposition, Pt-Ru-Co, Pt-Ru-Ni",

author = "Jihye Kim and Poliquit, \{Beta Zenia\} and Nam, \{Ho Seong\} and Kim, \{Sang Hern\} and Lee, \{Yong Min\} and Kim, \{Kwang Man\} and Ko, \{Jang Myoun\}",

note = "Funding Information: This research was financially supported by the Ministry of Education, Science Technology (MEST) and National Research Foundation of Korea (NRF) through the Human Resource Training Project for Regional Innovation.",

year = "2012",

month = jan,

doi = "10.1016/j.cap.2011.06.014",

language = "English",

volume = "12",

pages = "254--258",

journal = "Current Applied Physics",

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TY - JOUR

T1 - Electrochemical activities of Pt-Ru-Co and Pt-Ru-Ni electrocatalysts supported by a carbon fiber web

AU - Kim, Jihye

AU - Poliquit, Beta Zenia

AU - Nam, Ho Seong

AU - Kim, Sang Hern

AU - Lee, Yong Min

AU - Kim, Kwang Man

AU - Ko, Jang Myoun

N1 - Funding Information: This research was financially supported by the Ministry of Education, Science Technology (MEST) and National Research Foundation of Korea (NRF) through the Human Resource Training Project for Regional Innovation.

PY - 2012/1

Y1 - 2012/1

N2 - Dynamic cyclic voltammetry is performed as functions of cycle number and potential window for the electrodeposition of Pt-Ru-Co and Pt-Ru-Ni catalysts on a carbon fiber (CF) web. Surface morphologies of the electrodeposited catalysts are observed by a scanning electron microscope. The electrochemical activity in methanol oxidation is examined by the cyclic voltammetry using a mixed aqueous solution of methanol as an electrolyte component. As the cycle number increases, both the current density and the amount of the electrodeposited metallic particles on the CF web are increased. The Pt-Ru-Ni/CF catalyst prepared in the potential range of -0.6 to 0.2 V and from the 1:2:2 mixed solution of H 2PtCl6, RuCl3·3H2O, and Ni(NO3)2·6H2O, respectively, shows the higher current density, corresponding to the higher catalytic activity.

AB - Dynamic cyclic voltammetry is performed as functions of cycle number and potential window for the electrodeposition of Pt-Ru-Co and Pt-Ru-Ni catalysts on a carbon fiber (CF) web. Surface morphologies of the electrodeposited catalysts are observed by a scanning electron microscope. The electrochemical activity in methanol oxidation is examined by the cyclic voltammetry using a mixed aqueous solution of methanol as an electrolyte component. As the cycle number increases, both the current density and the amount of the electrodeposited metallic particles on the CF web are increased. The Pt-Ru-Ni/CF catalyst prepared in the potential range of -0.6 to 0.2 V and from the 1:2:2 mixed solution of H 2PtCl6, RuCl3·3H2O, and Ni(NO3)2·6H2O, respectively, shows the higher current density, corresponding to the higher catalytic activity.

KW - Carbon fiber web

KW - Cyclic voltammetry

KW - Electrodeposition

KW - Pt-Ru-Co

KW - Pt-Ru-Ni

UR - https://www.scopus.com/pages/publications/80054801449

U2 - 10.1016/j.cap.2011.06.014

DO - 10.1016/j.cap.2011.06.014

M3 - Article

AN - SCOPUS:80054801449

SN - 1567-1739

VL - 12

SP - 254

EP - 258

JO - Current Applied Physics

JF - Current Applied Physics

IS - 1

ER -

Electrochemical activities of Pt-Ru-Co and Pt-Ru-Ni electrocatalysts supported by a carbon fiber web

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Keywords

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