Efficient removal of Cs ion by electrochemical adsorption and desorption reaction using NiFe Prussian blue deposited carbon nanofiber electrode

Prussian blue (PB) analog (NiFe, CoFe, FeFe, and commercial(cPB)) decorated carbon nanofiber (CNF) electrodes were synthesized by the drop casting method in this study to investigate the interaction between PB and CNF for the electrochemical adsorption (EA) and electrochemical desorption (ED) of Cs ion (Cs⁺). The adhesion of PB on the electrode and the EA and ED of Cs⁺ were substantially higher when the CNF electrode was used, compared with the fluorine-doped tin oxide supporting electrode. The use of CNF led to the smooth occurrence of EA and ED of Cs⁺, where the reported efficiency was: NiFe > FeFe > cPB. The EA and ED of Cs⁺ on NiFe decorated CNF (C-NiFe) were strongly affected by the loading amount of NiFe. Although the strongest EA capacity was identified when 1 mg of NiFe was used, it decreased as the loading amount of NiFe increased. Thus, the EA of Cs⁺ occurs under the reduction of NiFe with some Fe(III) reduced to Fe(II) of NiFe, thus inducing more adsorption of Cs⁺. Overall, we confirmed that the C-NiFe electrode with appropriate thickness of NiFe layer is potentially an excellent adsorbent for Cs removal.