Effect of annealing temperature and ambient gas on phosphorus doped p-type ZnO

Dae Kue Hwang, Min Suk Oh, Jae Hong Lim, Chang Goo Kang, Seong Ju Park

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Abstract

The authors report on the thermal activation of phosphorus doped p -type ZnO thin films grown by radio frequency magnetron sputtering. The p -type ZnO was produced by activating phosphorus doped ZnO thin films in N2, Ar, or O2 ambients. The hole concentration of the p -type ZnO, prepared in an O2 ambient, showed a lower hole concentration compared to samples annealed in N2 and Ar ambients. The activation energies of the phosphorus dopant in the p -type ZnO under different ambient gases indicate that phosphorus atoms replace oxygen atoms in the ZnO to form PO which acts as an acceptor.

Original languageEnglish
Article number021106
JournalApplied Physics Letters
Volume90
Issue number2
DOIs
StatePublished - 2007

Bibliographical note

Funding Information:
This work was partially supported by the Ministry of Science and Technology through the National Research Laboratory Program in Korea, GTI (GIST Technology Initiative), and AOARD (Asian Office of Aerospace Research and Development).

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