Abstract
Herein, we report a mild and practical method for the deuteration of alkyl and aryl bromides by a thiyl radical catalyst and halogen-atom transfer (XAT) using disulfides and silanes under visible-light irradiation. In this study, various organic bromides such as 1°, 2°, and 3°-alkyl bromides and aryl bromides were converted to deuterated products in good to excellent yields and D-incorporation.
| Original language | English |
|---|---|
| Pages (from-to) | 5526-5529 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 60 |
| Issue number | 42 |
| DOIs | |
| State | Published - 26 Apr 2024 |
Bibliographical note
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