Crystal structure of AlPCl8

Hyeonjin Seo; Seungyong Shin; Seung Tae Hong

doi:10.1107/S2056989024010661

Crystal structure of AlPCl₈

Hyeonjin Seo
, Seungyong Shin
, Seung Tae Hong

Department of Energy and Science and Engineering

Daegu Gyeongbuk Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl₄)[AlCl₄] or AlPCl₈, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms.

Original language	English
Pages (from-to)	1280-1282
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	80
Issue number	Pt 12
DOIs	https://doi.org/10.1107/S2056989024010661
State	Published - 1 Nov 2024

Bibliographical note

Publisher Copyright:
© 2024 International Union of Crystallography. All rights reserved.

Keywords

aluminium phosphorus chloride
aluminium(III) chloride
crystal structure
phosphorus(V) chloride
single-crystal

Access to Document

10.1107/S2056989024010661

Cite this

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abstract = "The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms.",

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N2 - The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms.

AB - The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl4)[AlCl4] or AlPCl8, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms.

KW - aluminium phosphorus chloride

KW - aluminium(III) chloride

KW - crystal structure

KW - phosphorus(V) chloride

KW - single-crystal

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JF - Acta Crystallographica Section E: Crystallographic Communications

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