Anion receptor-coated separator for lithium-ion polymer battery

Je An Lee; Jun Young Lee; Myung Hyun Ryou; Gi Beom Han; Je Nam Lee; Dong Jin Lee; Jung Ki Park; Yong Min Lee

doi:10.1007/s10008-010-1149-y

Anion receptor-coated separator for lithium-ion polymer battery

Je An Lee, Jun Young Lee, Myung Hyun Ryou, Gi Beom Han, Je Nam Lee, Dong Jin Lee, Jung Ki Park, Yong Min Lee

Department of Energy and Science and Engineering

Korea Advanced Institute of Science and Technology

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Anion receptor-coated separators were prepared by coating poly(ethylene glycol) borate ester (PEGB) as an anion receptor and poly(vinyl acetate) (PVAc) as a good adhesive material towards electrodes onto microporous polyethylene (PE) separators. Gel polymer electrolytes were fabricated by soaking them in an liquid electrolyte, 1 M LiPF ₆ in EC/DEC/PC (30/65/5, wt.%). As the weight ratio of PEGB to PVAc in a coating layer increased, gel polymer electrolytes showed higher cationic conductivity and electrochemical stability. The cationic conductivity and electrochemical stability of the gel polymer electrolyte based on coated separator with PVAc/PEGB (2/5, weight ratio) could reach 2.8×10 ^-4 S cm ^-1 and 4.8 V, respectively. Lithium-ion polymer cells (LiCoO ₂/graphite) based on gel polymer electrolytes with and without PEGB were assembled, and their electrochemical performances were evaluated.

Original language	English
Pages (from-to)	753-757
Number of pages	5
Journal	Journal of Solid State Electrochemistry
Volume	15
Issue number	4
DOIs	https://doi.org/10.1007/s10008-010-1149-y
State	Published - Apr 2011

Bibliographical note

Funding Information:
This work was supported by the IT R&D program of MKE/IITA (Core Lithium Secondary Battery Anode Materials for Next Generation Mobile Power Module, 2008-F-019-01)

Keywords

Anion receptor
Coated separator
Gel polymer electrolyte
Lithium-ion polymer battery
PEG-borate ester

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10.1007/s10008-010-1149-y

Cite this

@article{e5f451b87f2f48e89394c248f53d0172,

title = "Anion receptor-coated separator for lithium-ion polymer battery",

abstract = "Anion receptor-coated separators were prepared by coating poly(ethylene glycol) borate ester (PEGB) as an anion receptor and poly(vinyl acetate) (PVAc) as a good adhesive material towards electrodes onto microporous polyethylene (PE) separators. Gel polymer electrolytes were fabricated by soaking them in an liquid electrolyte, 1 M LiPF 6 in EC/DEC/PC (30/65/5, wt.\%). As the weight ratio of PEGB to PVAc in a coating layer increased, gel polymer electrolytes showed higher cationic conductivity and electrochemical stability. The cationic conductivity and electrochemical stability of the gel polymer electrolyte based on coated separator with PVAc/PEGB (2/5, weight ratio) could reach 2.8×10 -4 S cm -1 and 4.8 V, respectively. Lithium-ion polymer cells (LiCoO 2/graphite) based on gel polymer electrolytes with and without PEGB were assembled, and their electrochemical performances were evaluated.",

keywords = "Anion receptor, Coated separator, Gel polymer electrolyte, Lithium-ion polymer battery, PEG-borate ester",

author = "Lee, \{Je An\} and Lee, \{Jun Young\} and Ryou, \{Myung Hyun\} and Han, \{Gi Beom\} and Lee, \{Je Nam\} and Lee, \{Dong Jin\} and Park, \{Jung Ki\} and Lee, \{Yong Min\}",

note = "Funding Information: This work was supported by the IT R\&D program of MKE/IITA (Core Lithium Secondary Battery Anode Materials for Next Generation Mobile Power Module, 2008-F-019-01)",

year = "2011",

month = apr,

doi = "10.1007/s10008-010-1149-y",

language = "English",

volume = "15",

pages = "753--757",

journal = "Journal of Solid State Electrochemistry",

issn = "1432-8488",

publisher = "Springer Verlag",

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TY - JOUR

T1 - Anion receptor-coated separator for lithium-ion polymer battery

AU - Lee, Je An

AU - Lee, Jun Young

AU - Ryou, Myung Hyun

AU - Han, Gi Beom

AU - Lee, Je Nam

AU - Lee, Dong Jin

AU - Park, Jung Ki

AU - Lee, Yong Min

N1 - Funding Information: This work was supported by the IT R&D program of MKE/IITA (Core Lithium Secondary Battery Anode Materials for Next Generation Mobile Power Module, 2008-F-019-01)

PY - 2011/4

Y1 - 2011/4

N2 - Anion receptor-coated separators were prepared by coating poly(ethylene glycol) borate ester (PEGB) as an anion receptor and poly(vinyl acetate) (PVAc) as a good adhesive material towards electrodes onto microporous polyethylene (PE) separators. Gel polymer electrolytes were fabricated by soaking them in an liquid electrolyte, 1 M LiPF 6 in EC/DEC/PC (30/65/5, wt.%). As the weight ratio of PEGB to PVAc in a coating layer increased, gel polymer electrolytes showed higher cationic conductivity and electrochemical stability. The cationic conductivity and electrochemical stability of the gel polymer electrolyte based on coated separator with PVAc/PEGB (2/5, weight ratio) could reach 2.8×10 -4 S cm -1 and 4.8 V, respectively. Lithium-ion polymer cells (LiCoO 2/graphite) based on gel polymer electrolytes with and without PEGB were assembled, and their electrochemical performances were evaluated.

AB - Anion receptor-coated separators were prepared by coating poly(ethylene glycol) borate ester (PEGB) as an anion receptor and poly(vinyl acetate) (PVAc) as a good adhesive material towards electrodes onto microporous polyethylene (PE) separators. Gel polymer electrolytes were fabricated by soaking them in an liquid electrolyte, 1 M LiPF 6 in EC/DEC/PC (30/65/5, wt.%). As the weight ratio of PEGB to PVAc in a coating layer increased, gel polymer electrolytes showed higher cationic conductivity and electrochemical stability. The cationic conductivity and electrochemical stability of the gel polymer electrolyte based on coated separator with PVAc/PEGB (2/5, weight ratio) could reach 2.8×10 -4 S cm -1 and 4.8 V, respectively. Lithium-ion polymer cells (LiCoO 2/graphite) based on gel polymer electrolytes with and without PEGB were assembled, and their electrochemical performances were evaluated.

KW - Anion receptor

KW - Coated separator

KW - Gel polymer electrolyte

KW - Lithium-ion polymer battery

KW - PEG-borate ester

UR - https://www.scopus.com/pages/publications/79955920087

U2 - 10.1007/s10008-010-1149-y

DO - 10.1007/s10008-010-1149-y

M3 - Article

AN - SCOPUS:79955920087

SN - 1432-8488

VL - 15

SP - 753

EP - 757

JO - Journal of Solid State Electrochemistry

JF - Journal of Solid State Electrochemistry

IS - 4

ER -

Anion receptor-coated separator for lithium-ion polymer battery

Abstract

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Keywords

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