Activated carbon made from cow dung as electrode material for electrochemical double layer capacitor

Dhrubajyoti Bhattacharjya, Jong Sung Yu

Research output: Contribution to journalArticlepeer-review

297 Scopus citations

Abstract

Cow dung is one of the most abundant wastes generated on earth and has been traditionally used as fertilizer and fuel in most of the developing countries. In this study activated carbon is synthesized from cow dung by a modified chemical activation method, where partially carbonized cow dung is treated with KOH in different ratio. The synthesized activated carbon possesses irregular surface morphology with high surface area in the range of 1500-2000 m 2 g-1 with proper amount of micropore and mesopore volume. In particular, we demonstrate that the surface morphology and porosity parameters change with increase in KOH ratio. These activated carbons are tested as electrode material in two-electrode symmetric supercapacitor system in non-aqueous electrolyte and found to exhibit high specific capacitance with excellent retention of it at high current density and for long term operation. In particular, the activated carbon synthesized at 2:1 ratio of KOH and the pre-carbonized char shows the best performance with specific capacitance of 124 F g-1 at 0.1 A g-1 and retains up to 117 F g-1 at 1.0 A g-1 current density. The performance is attributed to high surface area along with optimum amount of micropore and mesopore volume.

Original languageEnglish
Pages (from-to)224-231
Number of pages8
JournalJournal of Power Sources
Volume262
DOIs
StatePublished - 15 Sep 2014

Bibliographical note

Funding Information:
This work was supported by NRF grant ( NRF 2010-0029245 ) and Global Frontier R&D Program on Center for Multiscale Energy System ( NRF 2011-0031571 ) funded by the Ministry of Education, Science and Technology through the National Research Foundation of Korea . The authors also would like to thank Dana Kim and Nitin Chaudhari for providing the cow dung, and Hyeon-yeol Park and Jong-deok Park for FE-SEM and BET analysis.

Keywords

  • Activation
  • Cow dung
  • Organic electrolyte
  • Supercapacitor
  • Two-electrode system

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